آمار
| تعداد نشریات | 13 |
| تعداد شمارهها | 646 |
| تعداد مقالات | 6,748 |
| تعداد مشاهده مقاله | 9,373,893 |
| تعداد دریافت فایل اصل مقاله | 8,744,264 |
Study of kinetics, isotherms and thermodynamics of lead adsorption from aqueous solutions using Lignocellulose Nano-fibers (LCNFs) | ||
| Environmental Resources Research | ||
| دوره 8، شماره 1، فروردین 2020، صفحه 64-82 اصل مقاله (757.9 K) | ||
| نوع مقاله: Research Paper | ||
| شناسه دیجیتال (DOI): 10.22069/ijerr.2020.5091 | ||
| نویسندگان | ||
| S. Rastgar1؛ H. Rezaei* 2؛ H. Yousefi3 | ||
| 1Ph.D candidate, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran | ||
| 2Assistant Professor, Department of Environmental Pollution, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran | ||
| 3Associate Professor, Department of Wood and Paper Engineering, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran | ||
| چکیده | ||
| The surface adsorption of heavy metals in effluents with nanoparticles is today a suitable method for effluents treatment. In the present study, lignocellulose nano-fibers (LCNFs) were used as natural adsorbent for lead adsorption. The aim was to evaluate lead adsorption using adsorption isotherms, kinetics and thermodynamics. Fourier TransformInfrared Spectroscopy (FT-IR) and Transmission Electron Microscopy (TEM) were employed to determine the chemical and structural properties of this adsorbent. To study the adsorption isotherm, two-parameter models of Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich were compared and three-parameter models of Redlich-Peterson and Sips and maximum correlation coefficient (R2) were selected as the best isotherm model for lead adsorption, which was obtained for the Langmuir model at 0.9997 and the Redlich-Peterson model at 0.9338. Therefore, the data were consistent with both models but were better described by the Langmuir model, indicating homogeneity of the adsorbent surface. In addition, reaction kinetic models, including pseudo-zero-order, pseudo-firstorder, pseudo-second-order and pseudo-third-order as well as the diffusion kinetic models including intra-particle diffusion and Elovich were investigated for adsorption reaction. The maximum correlation coefficient (R2=1) was related to the pseudo-second-order model; therefore, the lead adsorption by LCNFs was of a chemical type. The results obtained from the calculation of thermodynamic parameters such as Gibbs free energy (ΔG), enthalpy (ΔH◦), and entropy (ΔS◦) respectively showed spontaneity, exothermicity, and increased irregularities of the reaction. This study showed that LCNF is suitable for the adsorption of lead and as such could be used as a cost-effective adsorbent in the process of industrial wastewater treatment. | ||
| کلیدواژهها | ||
| Adsorption؛ isotherm؛ kinetics؛ lignocellulose Nano-fibers (LCNFs)؛ lead | ||
| مراجع | ||
|
Afzal Kamboh, M., Wan Ibrahim, W.A., and Nodeh, H.R. 2016. The removal of organophosphorus pesticides from water using a new amino-substituted calixarene-based magnetic sporopollenin. New Journal of Chemistry, 4 (40), 3130-3148.
Aharoni, C., and Tompkins, F. 1970. Kinetics of adsorption and desorption and the Elovich equation. Adv. Catal. Relat. Subj. 21, 1-49.
Ahmad, A.L., Sumathi, S., and Hameed, B.H. 2005. Adsorption of residue oil from palm oil mill, effluent using powder and flake chitosan: equilibrium and kinetic studies. Water Res. 39 (12), 2483-2494.
Alam Khan, T., Mukhlif, A.A., Khan, E.A., and Sharma, D. 2016. Isotherm and kinetics modeling of Pb(II) and Cd(II) adsorptive uptake from aqueous solution by chemically modified green algal biomass, 2, 117.
Anirudhan, T.S., Deepa, J.R., and Christa, J. 2016. Nanocellulose/nanobentonite composite anchored with multi-carboxyl functional groups as an adsorbent for the effective removal of Cobalt(II) from nuclear industry wastewater samples, Journal of colloid and interface science, 467, 307-320.
Arvind, J., Bhattacharya, G., Keerthana, B., Soud, M., and Nachammai, S. 2017. Removal of nickel from synthetic waste water using gooseberry seeds as biosorbent, Journal of bioremediation and sustainable technologies for cleaner environment, 2, 103-118,
Ayanda, O.S., Fatoki, O.S., Adekola, F.A., and Ximba, B.J. 2013. Kinetics and equilibrium models for the sorption of tributyltin to nZnO, activated carbon and nZnO/activated carbon composite in artificial seawater, Marine pollution bulletin, 72 (1), 222-230.
Azmi, N.S., and Yunos, K.F.M. 2014. Wastewater Treatment of Palm Oil Mill Effluent (POME) by Ultrafiltration Membrane Separation Technique Coupled with Adsorption Treatment as Pretreatment. Agriculture and agricultural Science procedia. 2, 257-264.
Ballav, N., Debnath, S., Pillay, K., and Maity, A. 2015. Efficient removal of reactive black from aqueous solution using polyaniline coated ligno-cellulose composite as a potential adsorbent, Journal of molecular liquids, 209, 387-396.
Belala, Z., Jeguirim, M., Belhachemi, M., Addoun, F., and Trouvé, G. 2011. Biosorption of basic dye from aqueous solutions by date stones and palm-trees waste: kinetic, equilibrium and thermodynamic studies. Desalination. 271 (1-3), 80-87.
Betancur, M., Bonelli, P.R., Velásquez, J.A., and Cukierman, A.L. 2009. Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: Effect of demineralization, J. Bioresours. Technol. 100 (3), 1130-1137.
Chowdhury, Z.Z., Zain, S.M., Khan, R.A., and Islam, M.S. 2012a. Preparation and characterizations of activated carbon from kenaf fiber for equilibrium adsorption studies of copper from wastewater. Korean J. Chem. Eng. 29 (9), 1187-1195.
Chowdhury, Z.Z., Zain, S.M., Khan, R.A., Rafique, R.F., and Khalid, K. 2012b. Batch and fixed bed adsorption studies of lead (II) cations from aqueous solutions onto granular activated carbon derived from Mangostana garcinia shell, BioResources. 7 (3), 2895-2915.
Duan, S., Tang, R., Xue, Z., Zhang, X., Zhao, Y., Zhang, W., Zhang, J., Wang, B., Zeng, S., and Sun, D. 2015. Effective removal of Pb (II) using magnetic Co 0.6 Fe 2.4 O 4 micro-particles as the adsorbent: synthesis and study on the kinetic and thermodynamic behaviors for its adsorption. Colloids Surf. A: Physicochem. Eng. Aspects. 469, 211-223.
Elagiwu, S.E., Usman, L.A., Awolola, G.V., Adebayo, G.B., and Ajayi, R.M.K. 2009. Adsorption of pb(ll) from aqueous solution by activated carbon prepared from Cow Dung, J. Adv. Natur. Sci. 3 (3), 442-446.
Ge, Y., Wu, S., Qin, L., and Zhili, L. 2016. Conversion of organosolv lignin into an efficient mercury ion adsorbent by a microwave-assisted method, Journal of the taiwan institute of chemical engineers, 63, 500-505.
Ho, Y.S., and McKay, G. 2002. Application of kinetic models to the sorption of copper (II) on to peat, Adsorption science and technology, 20, 797-815.
Huang, G., Wanga, D., Mab, S., Chen, J., Jiang, L., and Wang, P. 2015. A new, low-cost adsorbent: Preparation, characterization, and adsorption behavior of Pb (II) and Cu (II), Journal of colloid and interface science, 445, 294-302.
Igberase, E., and Osifo, P.O. 2015. Equilibrium, kinetic, thermodynamic and desorption studies of cadmium and lead by polyaniline grafted cross-linked chitosan beads from aqueous solution, J. Ind. Eng. Chem. 26, 340-347.
Inagaki, S., Caretta, T., Alfaya, R.V., and Alfaya, A. 2013. Mexerica mandarin (Citrus nobilis) peel as a new biosorbent to remove Cu(II), Cd(II), and Pb(II) from industrial effluent. Desalin, Water Treat. 51 (28-30), 5537-5546.
Kardam, A., Rohit Raj, K., Srivastava, S., and Srivastava, M.M. 2014. Nanocellulose fibers for biosorption of Cadmium nichkel, and Lead ions from aqueous solution, Clean technology and environmental policy, 16 (2), 385-393.
Kiapiszewski, K., Siwinska-Stefanska, K., and Kolodynska, D. 2017. Preparation and characterization of novel TiO2/lignin and TiO2-SiO2/lignin hybrids and their use as functional biosorbents for Pb(II), Chemical Engineering Journal, 314, 169-181.
Kini Srinivas, M., Saidutta, M.B., Murty, V.R.C., and Kadoli Sandip, V. 2013. Adsorption of basic dye from aqueous solution using HCl treated sawdust (Lagerstroemia microcarpa): kinetic, modeling of equilibrium, thermodynamic, International Research Journal of Environment Sciences, 2 (8), 6-16.
Klapiszewski, L., Bartzak, P., and Jesionowski, T. 2017. Removal of lead (II) Removal of leadions by an adsorption process with the use of an advanced SiO2/lignin biosorbent, Polish Journal of Chemical Technology, 19 (1), 67-74.
Kolodynska, D., Halas, P., Franus, M., and Hubicki, Z. 2017. Zeolite properties improvement by chitosan modification-Sorption studies, Journal of industrial and engineering chemistry, 52, 187-196.
Largitte, L., Burdey, T., Tant, T., Dumensnill, P., and Lodewyckx, P. 2016. Comparison of the adsorption of lead by activated carbons from three lignocellulosic precursors, Journal of microporous and mesoporous materials, 219, 265-275.
Li, Q., Zhai, J., Zhang, W., Wang, M., and Zhou, J. 2007. Kinetic studies of adsorption of pb(ll), Cr(ll) and Cu(ll) from aqueous Solution by sawdust and modified peanut husk, Journal of hazardous materials, 14 (4), 163-167.
Lopicic, Z.R., Stojanovic, M.D, Marovic, S.B., Milojikovic, J.V., Mihajilovic, M.L., Radoicic, T.S., and Kijevcanin, M.L. 2016. Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics, Arabian journal of chemistry, 5, 120-129.
Mahajan, G., and Sud, D. 2013. Application of Ligno-Cellulosic Waste Materisal for heavy metal removal from aqueous metal ions removal ions removal from aqueous solution. Journal of environmental chemical engineering, 1 (4), 1020-1027.
Marciante1, M., and Murillo, M.S. 2017. Thermodynamic and Kinetic Properties of Shocks in Two-Dimensional Yukawa Systems, Journal of biological chemistry, 292 (3), 955-966.
Maurya, R., Ghosh, T., Paliwal, C., Shrivastav, A., Chokshi, K., Pancha, I., Ghos, A., and Mishra, S. 2014. Biosorption of Methylene Blue by De-Oiled Algal Biomass: Equilibrium, Kinetics and Artificial Neural Network Modelling. PLoS ONE 9(10): e109545. doi:10.1371/ journal.pone.0109545.
Melichova, Z., and Romada, L. 2013. Adsorption of pb2+ and Cu2+ Ions from Aqqueous Solution On Natural Bentonite, Poly. Environ. Stud. 22 (2), 457-464.
Mohammed, R.R. 2013. Decolorisation of biologically treated palm oil mill effluent (POME) using adsorption technique, IRJES. 2 (10), 1-11.
Nagpal,UMK. and Rezaei, H. 2010. Equilibrium sorption studies for Cu2+ and Pb2+ metal ions on three different biomasses, Current World Environment 5 (2), 243.
Nasiruddin Khan, M., Bhutto, S., Wasim, A.A., and Khushid, S. 2016. Removal studies of Lead activated carbon derived from Lignocellulose Mangifera indicaseed shell, Journal of toxicological and environmental chemistry, 57 (24), 11211-11220.
Nethaji, S., Sivasamy, A., and Mandel, A. 2013. Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass, International journal of environmental science and technology, 10 (2), 231-242.
Niknahad Gharmakher, H., Esfandyari, A., and Rezaei, H., 2018. Phytoremediation of cadmium and nickel using Vetiveria zizanioides, Environmental Resources Research 6 (1), 41-50.
Nuhoglu, Y., and Malkoc, E. 2009. Thermodynamic and kinetic studies for environmentally friendly Ni (II) biosorption using waste pomace of olive oil factory. Bioresour Technol. 100, 2375-2380.
Ozcan, A.S., Ozcan, A., Tunali, S., Akar, T., Kiran, I., and Gedikbey, T. 2007. Adsoorption potential of Lead (ll) Ions from Aqueous Solution onto Capisicum anuum Seeds, J. Sep. Sci. Tech. 42, 137-151.
Parhizgar, F., Alishahi, A., Varasteh, H., and Rezaee, H. 2017. Removing sodium dodecyl benzene sulfonate (SDBS) from aqueous solutions using chitosan, Journal of Polymers and the Environment 25 (3), 836-843.
Reddy, D.H.K., and Lee, S.M. 2013. Application of magnetic Chitosan Composites for the removal of Toxic metal and dyes from aqueous solution. Journal of advances in colloid and interface science, 201-202, 68-93.
Ren, H., Gao, Z., Wu, D., Jiang, J., Sun, Y., and Luo, C. 2016. Efficient Pb(II) removal using sodium alginate–carboxymethyl cellulose gel beads: Preparation, characterization, and adsorption mechanism, Carbohydrate polymers, 137, 402-409.
Rezaei, H., Kulkarni, SD. and Saptarshi, PG. 2011. Study of Physical Chemistry on Biosorption of Nickel by using Chlorella pyrenoidosa, Oriental Journal of Chemistry 27 (2), 595-602.
Salamat, S., Hadavifar,M., and Rezaei, H. 2019. Preparation of nanochitosan-STP from shrimp shell and its application in removing of malachite green from aqueous solutions Journal of Environmental Chemical Engineering 7 (5), 103328.
Saman, N., Joharib, K., Songa, S.T., Konga, H., Cheua, S.C., and Mat, H. 2017. High removal efficacy of Hg(II) and MeHg(II) ions from aqueous solution by organoalkoxysilane-grafted lignocellulosic waste biomass, Journal of chemosphere, 171, 19-30.
Sekar, M., Sakthi, V., and Rengaraj, S. 2004. Kinetics, equilibrium adsorption study of lead (ll) onto activated carbon prepared from coconut Shell, Journal of colloid and interface science, 79, 307-313.
Shahmohaammadi Kalagh, S., Babazadeh, H., Nazemi, A.H., and Manshuri, M. 2011. Isotherm and kinetic studies on adsorption of Pb, Zn and Cu by kaolinite caspian, J. Env. Sci.9 (2), 243-255.
Shahat, A., Awual, M.R., Abdul khaleque, M., and Alam, Z. 2015. Large-pore diameter nano-adsorbent and its application for rapid Lead (ll) detection and removal From aqueous medi, J. Chem. Eng. http://dx.doi.Org/10.1016/j/Cej.2015.03.073.
Shi, Y., Kong, X., Zhang, C., Chen, Y., and Hua, Y. 2013. Adsorption of soy isoflavones by activated carbon: Kinetics, thermodynamics and influence of soy oligosaccharides.Chem. Eng. J. 215-216, 113-121.
Shirzad Siboni, M., Samadi, M.T., Yang, J.K., and Lee, S.M. 2012. Photocatalytic removal of Cr (VI) and Ni (II) by UV/TiO2: kinetic study, Desalination and water treatment,40 (1-3), 77-83.
Sitthikhankaew, R., Chadwick, D., Assabumrungrat, S., and Laosiripojana, N. 2014. Effects of humidity, O2 and CO2 on H2S adsorption onto upgraded and KOH impregnated activated carbons, Fuel processtechnology, 124, 249-257.
Teoh, Y.P., Ali Khan, M., and Choong, T.S.Y. 2013. Kinetic and isotherm studies for lead adsorption from aqueous phase on carbon coated monolith, Chemical engineering journal, 217, 248-255.
Uslu, H. 2009. Adsorption equilibria of formic acid by weakly basic adsorbent AmberliteIRA-67: Equilibrium, kinetics, thermodynamic, Chem. Eng. 155 (1-2), 320-325.
Wang, L., Zhang, J., Zhao, R., Li, Y., Li, C., and Zhang, C. 2010. Adsorption of Pb(II) on activated carbon prepared from Polygonum orientale Linn.: kinetics isotherms, pH, and ionic strength studies, Bioresource Technology, 101, 5808-5814.
Yang, R., Aubercht, K.B., Ma, H., Wang, R., Grubbs, R.B., Hsiao, B.S., and Chu, B. 2014. Thiol-modiefiesd cellulose nanofibrous composite membranes for chromium (VI) and lead (ll) Adsorption, Journal of polymer, 55 (5), 1167-1176.
Yu, B., Zhang,Y., Shukla, A., and Shukla, S. 2001. Dorris Solution by Sawdust adsorption –removed of Lead and Comparison of its adsorption with Copper, Journal of hazardous materials, B. 84, 83-94.
Zawani, Z., Luqman, C.A., and Thomas, S.Y.C. 2009. Equilibrium, kinetics and thermodynamic studies: adsorption of remazol black 5 on the palm kernel shell activated carbon (PKSAC). Eur. J. Sci. Res. 3 (1), 763-771.
Zhang, X., Jin, C., Jiang, Y., Liu, G., and Wu, G. 2017. A novel gallic acid-grafted-lignin biosorbent for the selective eemoval of lead ions from aqueous solutions, Bioresources,12 (3), 210-218.
Zouiten, A., Beltifa, A., Van Loco, J., Ben Mansour, H., and Reyns, T. 2016. Ecotoxicological potential of antibiotic pollution–industrial wastewater: bioavailability, biomarkers, and occurrence in Mytilus galloprovincialis, Environmental science and pollution research. doi:10.1007/s11356-016-6713-2. | ||
|
آمار تعداد مشاهده مقاله: 350 تعداد دریافت فایل اصل مقاله: 505 |
||
سامانه مدیریت نشریات علمی. طراحی و پیاده سازی از سیناوب